Dimethylaluminumhydride reaction set: high-pressure rate coefficients k(T) = A Tn exp(-Ea/kT)
Reaction A Ea
sec-1 or cc molecule-1 sec-1 kcal/mol
(CH3)2AlH -> AlCH3 + CH4 4.854 x 1012 90.219
AlCH3 + CH4 -> (CH3)2AlH 1.111 x 10-10 70.742
(CH3)2AlH -> H3CAlCH2 + H2 5.218 x 1012 68.845
H3CAlCH2 + H2 -> (CH3)2AlH 5.675 x 10-11 6.822
(CH3)2AlH -> AlH + C2H6 3.107 x 1014 107.933
AlH + C2H6 -> (CH3)2AlH 1.786 x 10-09 77.321
H3CAlH + CH3 -> (CH3)2AlH * 2.522 x 10-11 0.253
(CH3)2 AlH -> (CH3) AlH + CH3 2.55 x 1013 77.050
* Loose transition states, treated with Gorin-like model

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